Something like this (i'm assuming your array is called nodes):

var targetNodeIndex : int;
var targetNode : GameObject;

//the function called by your back button
function GoBack()
{
  targetNodeIndex = nodes.length - 2;
  //retrieves the second to last node. Eg in a 5 node array - this returns node 4.
  targetNode = nodes[targetNodeIndex];
}

We use "length-2" because nodes.length will return the length of the array BUT in a 5 node length array the elements will be in indexes 0,1,2,3, and 4. So to get at the second to last node we need to access the index that is 2 less than the length.

Once you have retrieved your node just set the players transform to the same as the node trnasform.

You can create a List of MoveNodes, then use the List functions Add, Remove, etc. and its property Item for managing and accessing the items as you want. You can see an example here:

http://forum.unity3d.com/threads/79760-How-to-use-generics-in-unity-javascript?p=510611#post510611

The reference for the List methods and properties is here:

http://msdn.microsoft.com/en-us/library/6sh2ey19.aspx