Could not start compilation, Win32Exception

Just started my game up, I get this error.

Could not start compilationWin32Exception: ApplicationName='"C:\Users\***\Desktop\***'s Folder\Unity\Editor\Data\Mono\bin\mono.exe"', CommandLine='"C:\Users\***\Desktop\***'s Folder\Unity\Editor\Data\Mono\lib\mono\unity\us.exe"  @Temp/UnityTempFile-f63c0c50fa46f6d4baf35ba84472861c', CurrentDirectory='C:/Users/***/Desktop/Unity Games/New Unity Project/Assets/..'
System.Diagnostics.Process.Start_noshell (System.Diagnostics.ProcessStartInfo startInfo, System.Diagnostics.Process process)
System.Diagnostics.Process.Start_common (System.Diagnostics.ProcessStartInfo startInfo, System.Diagnostics.Process process)
System.Diagnostics.Process.Start ()
(wrapper remoting-invoke-with-check) System.Diagnostics.Process:Start ()
UnityEditor.Utils.Program.Start () (at C:/buildslave/unity/build/Editor/Mono/Utils/Program.cs:33)
UnityEditor.Scripting.Compilers.MonoScriptCompilerBase.StartCompiler (BuildTarget target, System.String compiler, System.Collections.Generic.List`1 arguments, Boolean setMonoEnvironmentVariables) (at C:/buildslave/unity/build/Editor/Mono/Scripting/Compilers/MonoScriptCompilerBase.cs:31)
UnityEditor.Scripting.Compilers.MonoScriptCompilerBase.StartCompiler (BuildTarget target, System.String compiler, System.Collections.Generic.List`1 arguments) (at C:/buildslave/unity/build/Editor/Mono/Scripting/Compilers/MonoScriptCompilerBase.cs:18)
UnityEditor.Scripting.Compilers.UnityScriptCompiler.StartCompiler () (at C:/buildslave/unity/build/Editor/Mono/Scripting/Compilers/UnityScriptCompiler.cs:58)
UnityEditor.Scripting.Compilers.ScriptCompilerBase.BeginCompiling () (at C:/buildslave/unity/build/Editor/Mono/Scripting/Compilers/ScriptCompilerBase.cs:47)

What does it mean? How do I fix it?

Never install programs to your desktop, the best place to put them is either in the root directory of the HDD, ie C:\Unity3D or under a folder such as C:\Program Files. I personally have Unity 5 installed at D:\GameDev\Unity3D. The less folders in the path, the easier the OS can call things as some programs have weird path name limitations.